Structurally defined zincated and aluminated complexes of ferrocene made by alkali-metal-synergistic synthesesReaction of ferrocene with 1 or 2 molar equiv of the synergistic-operative bimetallic sodium zincate base TMEDA·Na(μ-TMP)(μ-tBu)Zn(tBu) yields mainly mono- or dizincated complexes TMEDA·Na(μ-TMP)[μ-(C5H4)Fe(C5H5)]ZntBu (1) and [TMEDA·Na(μ-TMP)Zn(tBu)]2(C5H4)2Fe...
Synthetic and reactivity studies of hetero-tri-anionic sodium zincatesThe synthesis and characterisation of several sodium zincate complexes is reported....
Remote functionalisation via sodium alkylamidozincate intermediates : access to unusual fluorenone and pyridyl ketone reactivity patternsTreating fluorenone or 2-benzoylpyridine with the sodium zincate [(TMEDA)center dot Na(mu-Bu-t)(mu-TMP)Zn(Bu-t)] in hexane solution, gives efficient Bu-t addition across the respective organic substrate in a highly unusual 1,6-fashion,...
A highly efficient hydrogen generation electrolysis system using alkaline zinc hydroxide solution... Here in this work, we report for the first time the application of alkaline zinchydroxide solution (composed of sodium zincate and potassium zincate in NaOH and KOHsolutions, respectively) as an efficient, simple and recursive electrolyte for producing clean hydrogenthrough a continuous...
