Synthesis, characterization,and reactivity of fecomplexes containing cyclic diazadiphosphine ligands: the role ofthe pendant base in heterolytic cleavage of h2... Studies of H/D exchange by the complexes [1-H2]+, [2-H2]+, and [3-H2]+ carried out using H2 and D2 indicate that the relatively rapid H/D exchange observedfor [1-H2]+ and [2-H2]+ compared to [3-H2]+ is consistentwith intramolecular heterolytic cleavage of H2 mediatedby the pendant amine....
Synthesis of functionalizedfluorescent indenes fromelectron-rich α-aryl ketonitriles...bearing 1,3-dicyanogroups weresynthesized from electron-rich α-aryl ketonitriles in the presenceof K3Fe(CN)6 and NaOAc, possibly through tandemprocess involving dimerization, heterolytic cleavage of carbon–carbonbond, intermolecular coupling, and the subsequent intramolecular cyclization.The...
H2 activation using the first 1:1:1 hetero-tri(aryl)borane... This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases
Hydrogenation of carbon dioxideusing half-sandwichcobalt, rhodium, and iridium complexes: dft study on the mechanismand metal effect... All metal complexesare found to process a similar mechanism, which involves two mainsteps, the heterolytic cleavage of H2 and the hydride transfer.The...
