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Asymmetric dihydroxylation of c,c double bonds using catalytic amounts of osmium tetroxide, selenides, and airpeer reviewedSelenides, selenoxides, osmium tetroxide, and potassium osmate dihydrate are in equilibrium in aqueous tert-butanol containing potassium carbonate...

chimie - core.ac.uk - PDF: orbi.uliege.be

Publications scientifiques

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Catalytic asymmetric dihydroxylation of c,c double bonds with osmium tetroxide using selenoxides as co-oxidantspeer reviewedAsymmetric dihydroxylation of olefins has been achieved in good yields and ee's using potassium osmate dihydrate (K2OsO2(OH)(4), the pre-oxidant), (DHQD)(2)PHAL (the chiral ligand), potassium carbonate (the base) and selenoxides (the co-oxidants)...

général - core.ac.uk - PDF: orbi.uliege.be

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Production of transition metal oxidants through design and synthesis of polyanionic chelating ligands... Reaction of this with potassium osmate produces Os(VI)(η⁴-HMPA-DMP)O...

général - core.ac.uk - PDF: thesis.library.caltech.edu