Synthesis and reactivity of 4-oxo-5-trimethylsilanyl derived α-amino acids... The use of trimethylaluminium or catalytic tin(II) chloride gave novel 4-oxo-5-trimethylsilanyl derived amino acids in yields of 71–88%....
Synthesis, characterization and crystal structure of a 2-(diethylaminomethyl)indole ligated dimethylaluminium complex...[Al(CH3)2(C13H17N2)] (systematic name; {2-[(diethylamino)methyl]indol-1-yl-κ2N,N′}dimethylaluminium), was prepared by methane elimination from the reaction of 2-(diethylaminomethyl)indole and trimethylaluminium....
Enantioselective copper-catalyzed conjugate addition of trimethylaluminum to β,γ-unsaturated α-ketoamides: efficient access to γ-methyl-substituted carbonyl compoundsPicture perfect: By using the reagent trimethylaluminium and β,γ-unsaturated α-ketoamides, 1,4-adducts were obtained with perfect 1,4-regioselectivity and good to excellent yields and ee values....
Bis{μ-4,4′,6,6′-tetra-tert-butyl-2,2′-[n-(2-oxidoethyl)iminodimethylene]diphenolato}dialuminium(iii)... It was isolated from a reaction mixture of the parent ligand and trimethylaluminium in tetrahydrofuran....
