Photoinduced synthesis of block copolymers by combination of atom transfer radical polymerization and photoinduced radical oxidation/addition/deactivation... Thus, mono- or bi- bromide functional polystyrenes (PS-Br or Br-PS-Br) synthesized by light induced ATRP were used as macroinitiator for the living cationic polymerization of isobutyl vinyl ether via PROAD process to give the corresponding block copolymers....
Polymerization of vinyl ethers initiated by dendritic cations using flow microreactors... The carbocationic polymer end generated by polymerization of isobutyl vinyl ether was effectively trapped by various nucleophiles such as trimethyl(1-phenylvinyloxy)silane and allyltrimethylsilane to give polymers with very narrow molecular...
A new multifunctional initiator system for the living cationic polymerization of vinyl ethersCombination of hexa(chloromethyl)melamine (HCMM) and zinc chloride was found to be a multifunctional initiator system for the living cationic polymerization of isobutyl vinyl ether....
Achieving low-cost and accelerated living cationicpolymerization of isobutyl vinyl ether in microflow systemInthis work, we proposed and realized a strategy for fast andlow-cost living cationic polymerization of isobutyl vinyl ether (IBVE)based on temporary stability of propagating chain....
