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Heme photolysis occurs by ultrafast excited state metal-to-ring charge transfer.... The Hb*II state arises from porphyrin ring-to-iron back charge transfer to produce a porphyrin ground state configuration a nonequilibrium iron d-orbital population....

général - core.ac.uk - PDF: www.pubmedcentral.nih.gov

Heme photolysis occurs by ultrafast excited state metal-to-ring charge transfer ... The HbII∗ state arises from porphyrin ring-to-iron back charge transfer to produce a porphyrin ground state configuration a nonequilibrium iron d-orbital population....

Publications scientifiques

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Nuclear relaxation and spin dynamics in nmp tcnq

... The results show that the main source of nuclear relaxation is provided by localized electronic spins, associated with back charge transfer on the NMP stacks....

... Les résultats montrent que la principale source de relaxation nucléaire provient de spins électroniques localisés sur les chaines de NMP et associés à un transfert de charge incomplet...

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